Poly[disodium [diaquatri-μ2-oxalato-dimagnesium(II)]]

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The title compound, [Cu(2)(C(2)O(4))(2)(C(3)H(4)N(2))(2)](n), was obtained as an unexpected product under hydro-thermal conditions. The Cu(II) atom is in a Jahn-Teller-distorted octa-hedral environment formed by one imidazole N atom and five O atoms from three oxalate anions. The two independent oxalate anions are situated on centres of inversion and coordinate to the Cu(II) atom in two differe...

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In the title compound, {[Pr(2)(C(2)O(4))(3)(H(2)O)(4)]·2H(2)O}(n), the three-dimensional network structure has the Pr(III) ion coordinated by nine O atoms in a distorted tricapped trigonal-prismatic geometry. The coordinated and uncoordinated water mol-ecules inter-act with the carboxyl-ate O atoms to consolidate the network via O-H⋯O hydrogen bonds.

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Poly[[tetra­aqua­di-μ4-oxalato-μ2-oxalato-dineo­dymium(III)] dihydrate]

The title compound, {[Nd(2)(C(2)O(4))(3)(H(2)O)(4)]·2H(2)O}(n), was synthesized hydro-thermally in the presence of bis-(carb-oxy-ethyl-germanium) sesquioxide. It is isostructural with the corresponding Pr compound [Yang et al. (2009). Acta Cryst. E65, m1152-m1153]. The Nd(3+) cation is nine-coordinated and its coordination polyhedron can be described as a distorted tricapped trigonal prism. Two...

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Poly[diaqua-μ2-isonicotinato-μ2-oxalato-terbium(III)]

In the crystal structure of the title complex, [Tb(C(6)H(4)NO(2))(C(2)O(4))(H(2)O)(2)](n), the Tb(III) cation is coordinated by four O atoms from two oxalate ligands, two O atoms from two isonicotinate ligands and two O atoms from water mol-ecules within a distorted square-anti-prismatic coordination. The Tb(III) cation, the isonicotinate anion and the two crystallographically independent water...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808019508